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(p→d)π bonding in halosilanes; evidence from photoelectron spectroscopy

✍ Scribed by D.C Frost; F.G Herring; A Katrib; R.A.N McLean; J.E Drake; N.P.C Westwood

Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
472 KB
Volume
10
Category
Article
ISSN
0009-2614

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✦ Synopsis

Previous evidence for (p+d)* bonding ia some silyl halides is not considered adequate. Further resuks are presented on the photoelectron spectra of SiIi$l, SiH2c12, SiHCl3 and the previously determined SE4 which puts this on a fiier basis. 'c&Id b&due.to thcdifferent interaction of the .halogen p, qrbitals with the'% 3p orbitals, Therefore.

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Barriers to torsion around SiN bonds in
Barriers to torsion around SiN bonds in aminosilanes evidence for a small contribution from directional pπ-dπ bonding
✍ W.R. Jackson; T.G. Kee 📂 Article 📅 1972 🏛 Elsevier Science 🌐 French ⚖ 109 KB

There has been much recent speculation regarding the contributioa of pw -dv bonding to torsional barriers in formally single boodn. 1 Evidence for directional p,, -dv bonding in N-S bonds has come from a recent study of acyclic sulphonamidee.2 We have examined a series of aminosilaues in an attempt