✦ LIBER ✦

Barriers to torsion around SiN bonds in aminosilanes evidence for a small contribution from directional pπ-dπ bonding

✍ Scribed by W.R. Jackson; T.G. Kee

Publisher: Elsevier Science
Year: 1972
Tongue: French
Weight: 109 KB
Volume: 13
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)85166-2

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✦ Synopsis

There has been much recent speculation regarding the contributioa of pw -dv bonding to torsional barriers in formally single boodn.

1 Evidence for directional p,, -dv bonding in N-S bonds has come from a recent study of acyclic sulphonamidee.2 We have examined a series of aminosilaues in an attempt to see if similar directional bonding exists in Si-N bonds.