Oxyfunctionalization of polystyrene by hydrogen peroxide using non-heme iron catalysts
โ Scribed by McArthur, Shelley; Baird, Michael C.
- Book ID
- 124131582
- Publisher
- Elsevier Science
- Year
- 2014
- Tongue
- English
- Weight
- 618 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0014-3057
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๐ SIMILAR VOLUMES
## Abstract Nonโheme iron(III) complexes of 14โmembered tetraaza macrocycles have previously been found to catalytically decompose hydrogen peroxide to water and molecular oxygen, like the native enzyme catalase. Here the mechanism of this reaction is theoretically investigated by DFT calculations
The non-heme iron complex, Fe(TPAA = tris-[N-(2-pyridylmethyl)-2-aminoethyl]amine)(ClO 4 ) 2 , is a bad catalyst for the epoxidation of alkenes such as cyclooctene, cyclohexene and cis-stilbene and for the hydroxylation of alkanes such as adamantane by H 2 O 2 , when compared to the iron porphyrin F