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Heme/Hydrogen Peroxide Reactivity: Formation of Paramagnetic Iron Oxophlorin Isomers by Treatment of Iron Porphyrins with Hydrogen Peroxide

✍ Scribed by Kalish, Heather R.; Latos-Grażyński, Lechosław; Balch, Alan L.

Book ID
126951079
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
128 KB
Volume
122
Category
Article
ISSN
0002-7863

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The non-heme iron complex, Fe(TPAA = tris-[N-(2-pyridylmethyl)-2-aminoethyl]amine)(ClO 4 ) 2 , is a bad catalyst for the epoxidation of alkenes such as cyclooctene, cyclohexene and cis-stilbene and for the hydroxylation of alkanes such as adamantane by H 2 O 2 , when compared to the iron porphyrin F