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Ligand oxidation by activation of hydrogen peroxide with non-heme iron(III) complex

โœ Scribed by Senji Wada; Masakazu Iwase; Yoshihito Watanabe; Kouichiro Jitsukawa; Hideki Masuda; Hisahiko Einaga

Book ID
108405070
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
61 KB
Volume
67
Category
Article
ISSN
0162-0134

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๐Ÿ“œ SIMILAR VOLUMES

Hydrogen Peroxide Decomposition by a Non
Hydrogen Peroxide Decomposition by a Non-Heme Iron(III) Catalase Mimic: A DFT Study
โœ Willi Sicking; Hans-Gert Korth; Georg Jansen; Herbert deโ€…Groot; Reiner Sustmann ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 874 KB

## Abstract Nonโ€heme iron(III) complexes of 14โ€membered tetraaza macrocycles have previously been found to catalytically decompose hydrogen peroxide to water and molecular oxygen, like the native enzyme catalase. Here the mechanism of this reaction is theoretically investigated by DFT calculations