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ortho-Hydroxylation of benzoic acids with hydrogen peroxide at a non-heme iron center

✍ Scribed by Taktak, Sonia; Flook, Margaret; Foxman, Bruce M.; Que, Jr., Lawrence; Rybak-Akimova, Elena V.


Book ID
120565274
Publisher
Royal Society of Chemistry
Year
2005
Tongue
English
Weight
323 KB
Volume
42
Category
Article
ISSN
1359-7345

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The non-heme iron complex, Fe(TPAA = tris-[N-(2-pyridylmethyl)-2-aminoethyl]amine)(ClO 4 ) 2 , is a bad catalyst for the epoxidation of alkenes such as cyclooctene, cyclohexene and cis-stilbene and for the hydroxylation of alkanes such as adamantane by H 2 O 2 , when compared to the iron porphyrin F