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Oxidative cleavage of cyclopropanes. IV. Kinetics of the cleavage of arylcyclopropanes by mercuric acetate

โœ Scribed by Ouellette, Robert J.; Robins, Richard D.; South, Aubrey.

Book ID
127204877
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
717 KB
Volume
90
Category
Article
ISSN
0002-7863

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The stereochemistry of the cleavage of c
The stereochemistry of the cleavage of cyclopropanes by mercuric acetate
โœ Frederick R. Jensen; Dennis B. Patterson; Stephen E. Dinizo ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 236 KB

Because of the current interest2 in the stereochemistry of electrophilic aliphatic substitution, we with to report the results of reaction of 7,7-dimethylnorcarane, I, and norcarane with mercuric acetate. Cleavage of 1 in methanol (30 hrs, 25') after filtration to remove mercurous acetate (10%) and