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The stereochemistry of the cleavage of cyclopropanes by mercuric acetate

✍ Scribed by Frederick R. Jensen; Dennis B. Patterson; Stephen E. Dinizo

Book ID
104234806
Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
236 KB
Volume
15
Category
Article
ISSN
0040-4039

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✦ Synopsis

Because of the current interest2 in the stereochemistry of electrophilic aliphatic substitution, we with to report the results of reaction of 7,7-dimethylnorcarane, I, and norcarane with mercuric acetate. Cleavage of 1 in methanol (30 hrs, 25') after filtration to remove mercurous acetate (10%) and addition of chloride ion yielded 90 f 2% crude chloromercurial.

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