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Oxidative cleavage of 1-methylcycloalkanols by the Pb(IV) acetate-Cu(II) acetate system

✍ Scribed by G. I. Nikitin; N. I. Kapustina; S. S. Spektor; E. P. Kaplan

Book ID
112442140
Publisher
Springer
Year
1979
Tongue
English
Weight
408 KB
Volume
28
Category
Article
ISSN
1573-9171

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✍ Georgiy B Shul'pin; Georg SΓΌss-Fink; John R Lindsay Smith πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 694 KB

Higher alkanes (cyclohexane, n-pentane, n-heptane, methylbutane, 2-and 3methylpentanes, 3-methylhexane, cis-and trans-deealins) are oxidized at 20 Β°C by H202 in air in acetonitrile (or nitromethane) solution in the presence of the manganese(IV) salt [L2Mn203](PF6)2 (L = 1,4,7-trimethyl-1,4-7-triazac