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Benzyl cleavage in the oxidation of cycleanine by mercuric acetate

โœ Scribed by O. P. Sheichenko; O. N. Tolkachev


Book ID
112372899
Publisher
Springer
Year
1979
Tongue
English
Weight
289 KB
Volume
15
Category
Article
ISSN
0009-3130

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The stereochemistry of the cleavage of c
โœ Frederick R. Jensen; Dennis B. Patterson; Stephen E. Dinizo ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 236 KB

Because of the current interest2 in the stereochemistry of electrophilic aliphatic substitution, we with to report the results of reaction of 7,7-dimethylnorcarane, I, and norcarane with mercuric acetate. Cleavage of 1 in methanol (30 hrs, 25') after filtration to remove mercurous acetate (10%) and