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Oxidations of iron(II)/(III) by hydrogen peroxide: from aquo to enzyme

✍ Scribed by H.Brian Dunford


Book ID
108314942
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
159 KB
Volume
233-234
Category
Article
ISSN
0010-8545

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Efficient solvent-free iron (III) cataly
✍ Sandra E Martı́n; Analı́a Garrone πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 258 KB

Selective oxidation of secondary and benzylic alcohols was efficiently accomplished by H 2 O 2 under solvent-free condition catalyzed by FeBr 3 . Secondary alcohols are selectively oxidized even in the presence of primary ones. This method is high yielding, safe and operationally simple.