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Efficient solvent-free iron (III) catalyzed oxidation of alcohols by hydrogen peroxide

✍ Scribed by Sandra E Martı́n; Analı́a Garrone

Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
258 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis

Selective oxidation of secondary and benzylic alcohols was efficiently accomplished by H 2 O 2 under solvent-free condition catalyzed by FeBr 3 . Secondary alcohols are selectively oxidized even in the presence of primary ones. This method is high yielding, safe and operationally simple.

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Effective Oxidation of Benzylic and Alip
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Solvent-free reactions of alcohols with
Solvent-free reactions of alcohols with β-dicarbonyl compounds catalyzed by iron(III) chloride
✍ Yu Yuan; Zhuangzhi Shi; Xuan Feng; Xiangnong Liu 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 142 KB 👁 1 views

## Abstract The direct substitution of alcohols and β‐dicarbonyl compounds was catalyzed with FeCl~3~ under solvent‐free conditions. The catalyst loading could be decreased to 0.01 mol% at high activities. It was shown that the reaction proceeded in two steps via the etherification of the alcohols.