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Oxidation ofα-hydroxy acids and derivatives by Cr(VI) oxide

✍ Scribed by Sundaram, S. ;Venkatasubramanian, N.

Book ID: 112978021
Publisher: Springer-Verlag
Year: 1969
Tongue: English
Weight: 351 KB
Volume: 70
Category: Article
ISSN: 0370-0089
DOI: 10.1007/bf03046615

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## Abstract The oxidation of α‐hydroxy acids and α‐hydroxy ketones by Br(V) follows the rate‐law However, the former reaction exhibits a second‐order dependence on hydrogen ion concentration while the latter reaction has a third‐order dependence. A mechanism involving a slow formation of a bromate