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Oxidation of Two α-Hydroxy Acids by Vanadium(V)

✍ Scribed by Rômulo A. Ando; Cristiano Raminelli; Wagner J. Barreto; Keiko Takashima

Book ID
106213293
Publisher
Springer Vienna
Year
2003
Tongue
English
Weight
230 KB
Volume
134
Category
Article
ISSN
0026-9247

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A kinetic study of the oxidation of α-hy
A kinetic study of the oxidation of α-hydroxy acids and α-hydroxy ketones by potassium bromate
✍ R. Natarajan; N. Venkatasubramanian 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 346 KB

## Abstract The oxidation of α‐hydroxy acids and α‐hydroxy ketones by Br(V) follows the rate‐law However, the former reaction exhibits a second‐order dependence on hydrogen ion concentration while the latter reaction has a third‐order dependence. A mechanism involving a slow formation of a bromate