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Oxidation of benzyl alcohol with dioxygen catalyzed by an inorganic polymer–platinum complex

✍ Scribed by Xiao-Tun Yang; Yue Li; Mei-Yu Huang; Ying-Yan Jiang


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
220 KB
Volume
7
Category
Article
ISSN
1042-7147

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✦ Synopsis


An inorganic polymer-platinum complex, magnesiasupported polytitanzane-platinum complex (MgO-Ti-N-Pt), was prepared and used to catalyze the oxygenation of benzyl alcohol. It was found that this kind of catalyst has great activity and stability in the reaction. The objective product (benzaldehyde) was obtained in 100% yield in 6 hr under a moderate reaction temperature and atmospheric oxygen pressure. This inorganic polymer complex was also very stable during the reaction.


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