The kinetics of Ru(VI)-catalyzed oxidation of 2-propanol by hexacyanoferrate(III) was investigated in alkaline media using a spectrophotometric technique. The reaction shows first order in [Ru(VI)], a Michaelis-Menten-type dependence on [2-propanol], a fractional order in [Fe(CN) 3Γ 6 ] and a compli
Kinetic study of 2-propanol and benzyl alcohol oxidation by alkaline hexacyanoferrate(III) catalyzed by a terpyridyl ruthenium complex
β Scribed by Eric P. Kelson; Proma P. Phengsy
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 155 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0538-8066
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π SIMILAR VOLUMES
The oxidation kinetics of 2-butanol by alkaline hexacyanoferrate(III) catalyzed by sodium ruthenate has been studied spectrophotometrically. The initial rates method was used for kinetic analysis. The reaction rate shows a fractional-order in [hexacyanoferrate(III)] and [substrate] and a first-order
with respect to the catalyst concentration is first. The reaction mechanism supposes the formation of a complex between the substrate and the catalyst active form . Subsequently, the complex thus formed slowly decomposes in the rate determining step to give carbonium ions and ruthenium hydride, sinc
Osmium(VIII) Catalyzed Oxidation of Antimony(III) by Alkaline Hexacyanoferrate(III) and Analysis of Osmium(VIII) in Microamount by a Kinetic Method. -The osmium(VIII) catalyzed title reaction leading to Sb(V) and Fe(CN)4-6 via formation of a catalyst-oxidant complex is utilized for the analysis of
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