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Kinetics and mechanism of the oxidation of butane-2,3-diol by alkaline hexacyanoferrate (III), catalyzed by ruthenium trichloride

✍ Scribed by A. Mucientes Balado; F. Santiago Jimenez; F. J. Poblete Martín; R. Varón Castellanos

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
143 KB
Volume
29
Category
Article
ISSN
0538-8066

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✦ Synopsis

with respect to the catalyst concentration is first. The reaction mechanism supposes the formation of a complex between the substrate and the catalyst active form . Subsequently, the complex thus formed slowly decomposes in the rate determining step to give carbonium ions and ruthenium hydride, since ruthenium (III) abstracts a hydride ion from the ␣carbon atom of the diol .

In particular, the kinetics of oxidation of butane-2,3-diol has not been studied. In this article, we report the results of our experimental research on the

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