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ChemInform Abstract: Osmium(VIII) Catalyzed Oxidation of Antimony(III) by Alkaline Hexacyanoferrate(III) and Analysis of Osmium(VIII) in Microamount by a Kinetic Method.

โœ Scribed by P. L. TIMMANAGOUDAR; G. A. HIREMATH; S. T. NANDIBEWOOR


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Osmium(VIII) Catalyzed Oxidation of Antimony(III) by Alkaline Hexacyanoferrate(III) and Analysis of Osmium(VIII) in Microamount by a Kinetic Method.

-The osmium(VIII) catalyzed title reaction leading to Sb(V) and Fe(CN)4-6 via formation of a catalyst-oxidant complex is utilized for the analysis of microamounts of Os(VIII) ranging from 0.019 to 0.66 ยตg cm-3.

-(TIMMANAGOUDAR, P. L.; HIREMATH, G. A.;


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Oxidation of primary amines by bromamine
โœ S. Ananda; T. Demappa; N. M. Made Gowda ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 166 KB ๐Ÿ‘ 2 views

The kinetics of oxidation of the aliphatic primary amines, n-propylamine, n-butylamine, and isoamylamine, by N-sodio-N-bromobenznesulfonamide or bromamine-B (BAB), in the presence of osmium(VIII), has been studied in alkaline medium at 35ะŠC. In the presence of the catalyst, the experimental rate law