ChemInform Abstract: Osmium(VIII) Catalyzed Oxidation of Antimony(III) by Alkaline Hexacyanoferrate(III) and Analysis of Osmium(VIII) in Microamount by a Kinetic Method.
โ Scribed by P. L. TIMMANAGOUDAR; G. A. HIREMATH; S. T. NANDIBEWOOR
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
โฆ Synopsis
Osmium(VIII) Catalyzed Oxidation of Antimony(III) by Alkaline Hexacyanoferrate(III) and Analysis of Osmium(VIII) in Microamount by a Kinetic Method.
-The osmium(VIII) catalyzed title reaction leading to Sb(V) and Fe(CN)4-6 via formation of a catalyst-oxidant complex is utilized for the analysis of microamounts of Os(VIII) ranging from 0.019 to 0.66 ยตg cm-3.
-(TIMMANAGOUDAR, P. L.; HIREMATH, G. A.;
๐ SIMILAR VOLUMES
The kinetics of oxidation of the aliphatic primary amines, n-propylamine, n-butylamine, and isoamylamine, by N-sodio-N-bromobenznesulfonamide or bromamine-B (BAB), in the presence of osmium(VIII), has been studied in alkaline medium at 35ะC. In the presence of the catalyst, the experimental rate law