A magnesium oxide-supported polyalumazane-platinum complex was synthesized and characterized by X-ray photoelectron spectroscopy (XPS) and its performance toward the hydrogenation of norbornene. X P S data indicated that a large amount of platinum existed in a zero-valent state. The catalyst showed
Selective oxidation of tetrahydrofuran with molecular oxygen catalyzed by polyalumazane–platinum complexes
✍ Scribed by T.-J. Wang; Zhao-Hui Ma; Mei-Yu Huang; Ying-Yan Jiang
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 255 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1042-7147
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Magnesium oxide-supported polytitazane-platinum complex has been found to catalyze the oxygenation of diphenyl methanol with high yield and high selectivity at 140°C and 1 atrn 0,. The NIPt molar ratio, temperature and solvent had great influence on the activity of the ca talys t .
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