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Dioxygen Activation by a Manganese Complex Containing a Schiff Base: Selective Oxidation of an Imino to an Amido Group within the Salophen Ligand and Formation of a Hydroxy-Bridged MnIII-Polymer

✍ Scribed by Dr. Emma Gallo; Dr. Euro Solari; Prof. Dr. Carlo Floriani; Dr. Nazzareno Re; Prof. Dr. Angiola Chiesi-Villa; Dr. Corrado Rizzoli


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
393 KB
Volume
35
Category
Article
ISSN
0044-8249

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✦ Synopsis


The residue was extracted with Et,O (50 nil) to give a suspension of the red solid product in Et,O. The product was then filtered off and dried in vacuo (31 Yo). Recrystallization of the powder from Et,O:pyridine (90.10) yielded red crystals suitable for X-ray diffraction. Elemental analysis calcd for C,,H,,MnN,O,: