✦ LIBER ✦

Oxidation of amino acids by peroxomonophosphoric acid—a kinetic study

✍ Scribed by Ganesh P. Panigrahi; Ramesh C. Paichha

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 544 KB
Volume: 23
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550230406

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✦ Synopsis

Aliphatic amino acids are smoothly oxidized by peroxomonophosphoric acid (PMPA) in the pH region 6-10. Kinetic studies reveal second order dependence in the amino acid not observed hitherto in any of the PMPA oxidations. Dependence in PMPA is unity. Rate-pH profile yields a maximum around pH 8. The reaction path includes oxidation steps due to HzP05-and HPO;' . Second order dependence in the amino acid has been attributed to participation of two Zwitter-ionic molecules of the amino acid to form a nucleophile.

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