𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetics and mechanism of oxidation of hydrazinium ion with peroxomonophosphoric acid in acid perchlorate solutions and role of trace iodide ions

✍ Scribed by T. Peter Amala Dhas; D. K. Mishra; R. K. Mittal; Y. K. Gupta

Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
566 KB
Volume
23
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

The reaction of peroxomonophosphoric acid and hydrazinium ion in acid perchlorate solutions occurs as per stoichiometry (i), and the rate law (ii) at large [NzH~'],

(i)

where K& is the first acid dissociation constant of H3P05 and kl and kz are rate constants found to be 2.6 x s-' and 5.0 x lo-' M-' s-', respectively, at 35". The reaction is greatly catalyzed by iodide ions. The mechanism involves a redox cycle 1-/12 and the rate is independent of [N2H5'] in the presence of iodide ions. K& was found to be 0.55 M-' and independent of temperature.

πŸ“œ SIMILAR VOLUMES

Oxidation studies with peroxomonophospho
Oxidation studies with peroxomonophosphoric acid. II. A kinetic and mechanistic study of dimethyl sulfoxide oxidation in acid and alkaline media
✍ G. P. Panigrahi; Radhasyam Panda πŸ“‚ Article πŸ“… 1980 πŸ› John Wiley and Sons 🌐 English βš– 391 KB πŸ‘ 1 views

The kinetics of dimethyl sulfoxide (DMSO) oxidation by peroxomonophosphoric acid (PMPA) in aqueous medium a t 308 K and I = 0.4 mol/dm3 follow the rate expressions In the pH range from 0 to 2, where k l and kz are 5.092 X 10-1 dm3/mol sec and = 0, respectively; in the pH range from 4 to 7, where k2

Kinetics and mechanism of electron trans
Kinetics and mechanism of electron transfer reactions in aqueous solutions: Silver(I) catalyzed oxidation of aspartic acid by cerium (IV) in acid perchlorate medium
✍ Indu Sharma; Vijai Devra; Divya Gupta; C. M. Gangwal; P. D. Sharma πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 501 KB

Silver(1) catalyzed oxidation of aspartic acid by cerium(1V) was studied in acid perchlorate medium. The stoichiometry of the reaction is represented by the eq. (i) Dimeric cerium(IV) species has been indicated and employed in calculations of monomeric cerium(IV) species concentrations. The reactio

Kinetics and mechanism of the cerium (IV
Kinetics and mechanism of the cerium (IV) oxidation of Ξ±-Hydroxycycloalkanecarboxylic acids and cyclic alcohols in acidic perchlorate media
✍ Samir B. Hanna; Jeff Taylor Fenton πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons 🌐 English βš– 673 KB

## Abstract The Ce(IV) oxidation of the five‐, six‐, and seven‐membered ring α‐hydroxycycloalkanecarboxylic (C5, C6, and C7) acids to the corresponding cyclic ketones has been studied in acidic perchlorate media. The data may be interpreted in terms of a mechanism which involves fast preequilibrium

Mechanistic studies with positive iodine
Mechanistic studies with positive iodine: Kinetics of oxidation of thiocyanate ion by iodine monochloride and aqueous iodine in perchloric acid medium
✍ B. Thimme Gowda; J. Ishwara Bhat πŸ“‚ Article πŸ“… 1989 πŸ› John Wiley and Sons 🌐 English βš– 433 KB πŸ‘ 1 views

Kinetics of oxidation of thiocyanate ion (NCS-) by iodine monochloride and iodine has been studied in aqueous perchloric acid medium. The rates of oxidations followed the rate laws: Variations in ionic strength and dielectric constant of the medium had little effects on the rates of reactions with