Oxidation of mandelic acid by alkaline potassium permanganate. A kinetic study

✍ Scribed by Rafeek G. Panari; Ravindra B. Chougale; Sharanappa T. Nandibewoor

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 138 KB
• Volume: 11
• Category: Article
• ISSN: 0894-3230
• DOI: 10.1002/(sici)1099-1395(199807)11:7<448::aid-poc23>3.0.co;2-a

✦ Synopsis

The kinetics of the oxidation of mandelic acid (MA) by permanganate in aqueous alkaline medium at a constant ionic strength of 1.0 mol dm À3 were studied spectrophotometrically. The reaction shows first-order kinetics in [permanganate ion] and fractional order dependences in [MA] and [alkali]. Addition of products, manganate and aldehyde have no significant effect on the reaction rate. An increase in ionic strength and a decrease in dielectric constant of the medium increase the rate. The oxidation process in alkaline medium under the conditions employed in the present investigation proceeds first by formation of an alkali permanganate complex, which combines with mandelic acid to form another complex. The latter decomposes slowly followed by a fast reaction between the free radical of mandelic acid and another molecule of permanganate to give products. The reaction constants involved in the mechanism were derived. There is good agreement between the observed and calculated rate constants under different experimental conditions. The reaction was studied at different temperatures and activation parameters were computed with respect to the slow step of the proposed mechanism.