The kinetics of the oxidation of 1,10-phenanthroline (1,10-phen) by permanganate were investigated in alkaline medium. A first-order, fractional-order and zero-order dependence of the rate each in [MnO 4 Γ ], [1,10-phen] and [OH Γ ], respectively, was observed. The data suggest that the oxidation pr
ChemInform Abstract: Kinetics and Mechanism of Oxidation of L-Alanine by Alkaline Permanganate.
β Scribed by R. B. CHOUGALE; G. A. HIREMATH; S. T. NANDIBEWOOR
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 24 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The kinetics of the permanganate-hypophosphite redox reaction has been studied over a wide range of pH by using a stopped-flow technique. It has been found that the reaction leads to the formation of phosphite and orthophosphate, and that the molar ratio of the final products depends on pH. The prop
The kinetics of the oxidation of mandelic acid (MA) by permanganate in aqueous alkaline medium at a constant ionic strength of 1.0 mol dm Γ3 were studied spectrophotometrically. The reaction shows first-order kinetics in [permanganate ion] and fractional order dependences in [MA] and [alkali]. Addit
Kinetics and Mechanism of the Oxidation of Organic Sulfides by Bis(2,2' -bipyridyl)copper(II) Permanganate. -The H+-catalyzed oxidation of sulfides to sulfoxides using the title oxidant (BBCP) is found to be first order with respect to BBCP. Michaelis-Menten type kinetics are observed for the sulfi
The kinetic study of the oxidation of L-a-amino-n-butyric acid by permanganate ions has been carried out in buffered acid medium at pH = 1-3. using a spectrophotometric techriique An auto-catalytic effect has been observed in all cases due to Mn2+ ions formed as a product of the reaction. A first-or