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ChemInform Abstract: Kinetics and Mechanism of the Oxidation of Organic Sulfides by Bis(2,2′ -bipyridyl)copper(II) Permanganate.

✍ Scribed by A. BOHRA; P. K. SHARMA; K. K. BANERJI

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Kinetics and Mechanism of the Oxidation of Organic Sulfides by Bis(2,2' -bipyridyl)copper(II) Permanganate.

-The H+-catalyzed oxidation of sulfides to sulfoxides using the title oxidant (BBCP) is found to be first order with respect to BBCP. Michaelis-Menten type kinetics are observed for the sulfides. The oxidation is proposed to proceed via an intermediate complex possessing a covalent S-Mn-bond. -(BOHRA, A.; SHARMA, P. K.;

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v