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ChemInform Abstract: Oxidation of Organic Sulfides by Br2 and H2O2. Electrophilic and Free-Radical Processes.

✍ Scribed by Anna Bravo; Barbara Dordi; Francesca Fontana; Francesco Minisci


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
32
Category
Article
ISSN
0931-7597

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Kinetics and Mechanism of the Oxidation of Organic Sulfides by Bis(2,2' -bipyridyl)copper(II) Permanganate. -The H+-catalyzed oxidation of sulfides to sulfoxides using the title oxidant (BBCP) is found to be first order with respect to BBCP. Michaelis-Menten type kinetics are observed for the sulfi