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Kinetic and mechanistic studies on the oxidation of nitrite by peroxomonophosphoric acid

✍ Scribed by Ganesh Prasad Panigrahi; Ramanando Nayak

Publisher: John Wiley and Sons
Year: 1983
Tongue: English
Weight: 282 KB
Volume: 15
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550151004

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✦ Synopsis

The kinetics of oxidation of nitrite to nitrate by peroxornonophosphoric acid in aqueous acid medium have been studied. The observed monotonic fall in rate with increasing pH of the medium has been rationalized on the basis of proton-dissociation equilibria of the substrate as well as the oxidant species. It is found that only HNOz reacts with the different PMPA species.

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