✦ LIBER ✦

Kinetic studies on the oxidation of ascorbic acid by technetium(VII)

✍ Scribed by F. Grases; C. Genestar; E. Amat

Publisher: John Wiley and Sons
Year: 1986
Tongue: English
Weight: 297 KB
Volume: 18
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550180809

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✦ Synopsis

The pertechnetate ion oxidizes ascorbic acid in strong acid medium to form red species. A reaction mechanism has been developed which correctly predicts all the experimental facts. The results obtained support the postulate according to which the red species corresponds to a complex formed between Tc(V) and dehydroascorbic acid. The rate constants and Arrhenius parameters have been investigated.

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