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Oxidation of aliphatic amines by aqueous chlorine

✍ Scribed by L. Abia; X.L. Armesto; M.L. Canle; M.V. García; J.A. Santaballa

Book ID
104208275
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
432 KB
Volume
54
Category
Article
ISSN
0040-4020

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✦ Synopsis

The oxidation of aliphatic amines by aqueous chlorine has been studied. The kinetic behaviour is similar for primary, secondary and tertiary aliphatic amines, the elementary step being the transfer of chlorine from the hypochlorous acid molecule to the nitrogen of the f~e amino group. Chlorination of aliphatic primary and secondary amines involves some water molecules in the transition state. Inductive effects are also discussed.

📜 SIMILAR VOLUMES

ChemInform Abstract: Oxidation of Alipha
ChemInform Abstract: Oxidation of Aliphatic Amines by Aqueous Chlorine.
✍ L. ABIA; X. L. ARMESTO; M. CANLE L.; M. V. GARCIA; J. A. SANTABALLA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 1 views

Oxidation of Aliphatic Amines by Aqueous Chlorine. -A mechanistic study is done. The elementary step is the transfer of chlorine from the hypochlorous acid molecule to the nitrogen of the amino group. For primary and secondary amines H 2 O molecules are involved in the transition states.