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Oxidative δ-chlorination of aliphatic alcohols

✍ Scribed by G. I. Nikishin; N. I. Kapustina; A. V. Lisitsyn


Book ID
112445762
Publisher
Springer
Year
1986
Tongue
English
Weight
58 KB
Volume
35
Category
Article
ISSN
1573-9171

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Oxidation of Aliphatic Amines by Aqueous Chlorine. -A mechanistic study is done. The elementary step is the transfer of chlorine from the hypochlorous acid molecule to the nitrogen of the amino group. For primary and secondary amines H 2 O molecules are involved in the transition states.