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Oxidation of 1,4-Diols to Lactones 1

✍ Scribed by Stenberg, Virgil I.; Perkins, Robert J.


Book ID
118246980
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
268 KB
Volume
28
Category
Article
ISSN
0022-3263

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Highly chemoselective oxidation of 1,5-d
✍ T.Matthew Hansen; Gordon J. Florence; Priscilla Lugo-Mas; Jiehao Chen; Jason N. πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 146 KB

The selective oxidative conversion of a variety of highly functionalized 1Β°,2Β°-1,5-diols into the corresponding d-lactones has been effected simply and efficiently using a reagent system comprised of catalytic 2,2,6,6-tetramethylpiperidinooxy (TEMPO) and excess bis-acetoxyiodobenzene (BAIB).