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Highly Chemoselective Oxidation of 1,5-Diols to δ-Lactones with TEMPO/BAIB.

✍ Scribed by T. Matthew Hansen; Gordon J. Florence; Priscilla Lugo-Mas; Jiehao Chen; Jason N. Abrams; Craig J. Forsyth

Book ID
101942711
Publisher
John Wiley and Sons
Year
2003
Weight
118 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

📜 SIMILAR VOLUMES

Highly chemoselective oxidation of 1,5-d
Highly chemoselective oxidation of 1,5-diols to δ-lactones with TEMPO/BAIB
✍ T.Matthew Hansen; Gordon J. Florence; Priscilla Lugo-Mas; Jiehao Chen; Jason N. 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 146 KB

The selective oxidative conversion of a variety of highly functionalized 1°,2°-1,5-diols into the corresponding d-lactones has been effected simply and efficiently using a reagent system comprised of catalytic 2,2,6,6-tetramethylpiperidinooxy (TEMPO) and excess bis-acetoxyiodobenzene (BAIB).