The charge-transfer reactions of He: with Kr and Xe at thermal energy have been studied in a helium afterglow. The relative populations of the product Kr+ (2P,,z,,,) and Xe+ ('P 3,2,1,2) spin-orbit states were determined by using state-selective formation of rare gas halide excimen from ion-recombin
Oscillatory structures in bound-free fluorescence spectra of Xe2, Kr2 and Ar2
✍ Scribed by T. Möller; J. Stapelfeldt; M. Beland; G. Zimmerer
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 485 KB
- Volume
- 117
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Following sta~~wlccdve p&at synchrotron radiation uci~tion of Xq. Krz. and A+, oscillatory bound-rree su-uctures of Ihe firs1 continua were observed in time-resolved fluor-ce spectra The low-energy onx~s are assigned to 0: 4 X0,' transitions al lhe left turning point. Our resuh rule out earlier assignmcn~ of fluorescence fcalurcs to Ihe left turning poti observed under c-or a-particle cxciration of Kr and Ar. The shift of the txcillarory s~~ctures wih cxci~arion energy clcxriy suppa* our Wi~rnenL
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