Infrared spectra of methyl isocyanate isolated in Ar, Xe and N2 matrices
β Scribed by Igor Reva; Leszek Lapinski; Rui Fausto
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 683 KB
- Volume
- 976
- Category
- Article
- ISSN
- 0022-2860
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The absorption and magnetic circular dichroism (MCD) spectra of CGO isolated in Ar matrices have been measured in the visible and near-ultraviolet. The first two allowed bands (at 2326 and z 253 nm) show substantial negative .d terms. Sharp, weak vibronic structure showing clear evidence.of Jahn-Tel
Following sta~~wlccdve p&at synchrotron radiation uci~tion of Xq. Krz. and A+, oscillatory bound-rree su-uctures of Ihe firs1 continua were observed in time-resolved fluor-ce spectra The low-energy onx~s are assigned to 0: 4 X0,' transitions al lhe left turning point. Our resuh rule out earlier assi
FTIR spectra of the four isotopically substituted 1:1 complexes of acetonitrile and boron trifluoride were recorded in Ar, N 2 and Xe matrices. In Ar, previously unreported three vibrational modes of the complex were clearly observed. Several significant vibrational bands were also observed in N 2 a