FTIR spectra of the four isotopically substituted 1:1 complexes of acetonitrile and boron trifluoride were recorded in Ar, N 2 and Xe matrices. In Ar, previously unreported three vibrational modes of the complex were clearly observed. Several significant vibrational bands were also observed in N 2 a
FTIR spectra of the hydrogen-bonded complex H2CS⋯HCl in solid Ar, N2, and Xe
✍ Scribed by Eiichi Suzuki; Masahiro Yamazaki; Kenji Shimizu
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 309 KB
- Volume
- 797
- Category
- Article
- ISSN
- 0022-2860
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
One-to-one complexes between Na, K and Cs atoms and Hz0 have been studied by using matrix IR spectroscopy. Perturbed water submolecule vibrations were observed in the bending and stretching regions for each complex. The perturbed stretching vibration is assigned to the totally symmetric stretching m
## Abstract __Ab initio__ EOM‐CCSD calculations were performed to determine ^19^F,^1^H, ^19^F,^15^N and ^1^H,^15^N spin–spin coupling constants in model complexes FH–NH~3~ and FH–pyridine as a function of the F—H and F—N distances. The absolute value of ^1^__J__(F,H) decreases and that of ^1h^__J__
## Abstract The new H‐bonded complex [Os(bpy)~2~(CO)(EtO···H‐DMAP)][PF~6~]~2~, where DMAP = 4‐(dimethylamino)pyridine and bpy = 2,2′‐bipyridine, has been synthesized and characterized by X‐ray diffraction, IR, solution and solid‐state NMR spectroscopy. The complex shows a strong hydrogen bond betwe