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Orientation in the reaction of phenyllithium with 3-substituted pyridines

✍ Scribed by R.A. Abramovitch; A.D. Notation; Giam Choo Seng

Publisher: Elsevier Science
Year: 1959
Tongue: French
Weight: 152 KB
Volume: 1
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)82730-1

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✦ Synopsis

Reaeived 4 June 1959) A STKDY of the addition of phenyllithimn to 3-substituted pyridinez m.z undertaken to detemine the orientatfon of the entering phenyl group, . While this work was in progrees W&leg et al*' reported that the reaction of 3-phenylpyridine I(R -C H 65 ) with phenyllithium II wag aelective in giving 2,+iiphenylpyridine III(R -C&) exolusively. The formation of 2,3_diph~ipyridine IV(R = C H 65 f, which %iley et al, regard az less probable, ma not observed.

The addition of other nucleophilic reagent8 such az aodzmide 2*3 and butyl-

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