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Orientation effects on the rate and equilibrium constants for formation and decomposition of tetrahedral intermediates

✍ Scribed by Santry, Linda J.; McClelland, Robert A.


Book ID
126445384
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
503 KB
Volume
105
Category
Article
ISSN
0002-7863

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## Abstract Equilibrium constants for oxidations of cyclanols by cyclohexanone in benzene have been determined in the presence of aluminium isopropoxide. The free energies of the equilibrium (Ξ”__G__~ox~) are correlated with equilibrium constants for dissociation of cyanohydrins, rate constants for