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Alkyl group effects on the rate constants and equilibrium constants for formation of cyclic tetrahedral intermediates

✍ Scribed by Santry, Linda J.; Azer, Salwa.; McClelland, Robert A.

Book ID
126081754
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
811 KB
Volume
110
Category
Article
ISSN
0002-7863

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## Abstract Equilibrium constants for oxidations of cyclanols by cyclohexanone in benzene have been determined in the presence of aluminium isopropoxide. The free energies of the equilibrium (Ξ”__G__~ox~) are correlated with equilibrium constants for dissociation of cyanohydrins, rate constants for