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Organotitanium chemistry: VIII. X-ray crystal structures of bis(cyclopentylcyclopentadienyl)titanium dichloride and bis(cyclohexylcyclopentadienyl)titanium dichloride

โœ Scribed by Qichen Huang; Yanlong Qian; Youqi Tang; Shoushan Chen


Book ID
107811065
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
365 KB
Volume
340
Category
Article
ISSN
0022-328X

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## Abstract The syntheses of a series of lโ€methylโ€3โ€arylโ€substituted titanocene and zirconocene dichlorides are reported. These complexes are synthesized by the reaction of 2โ€ and 3โ€methylโ€6, 6โ€dimethylfulvenes (1:4) with aryllithium, followed by the reaction with TiCl~4~ยท2THF, ZrCl~4~ and (CpTiCl~