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Syntheses and Crystal Structures of Bis[(trimethylsilyl)tetramethylcyclopentadienyl]titanium Dichloride and Monochloride

✍ Scribed by Horáček, Michal; Gyepes, Róbert; Císařová, Ivana; Polášek, Miroslav; Varga, Vojtech; Mach, Karel


Book ID
111861808
Publisher
UOCHB
Year
1996
Tongue
English
Weight
90 KB
Volume
61
Category
Article
ISSN
0010-0765

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The new compounds La 4 Ti 2 O 4 Se 5 and La 6 Ti 3 O 5 Se 9 have been obtained from stoichiometric reactions of La, Ti, TiO 2 , and Se in fused-silica tubes at 1223 K. Potassium halide 6uxes were used to promote the crystallization. The compounds have been characterized by single-crystal X-ray di4ra