Electronic Structure of Bis(imino)pyridine Iron Dichloride, Monochloride, and Neutral Ligand Complexes: A Combined Structural, Spectroscopic, and Computational Study
✍ Scribed by Bart, Suzanne C.; Chłopek, Krzysztof; Bill, Eckhard; Bouwkamp, Marco W.; Lobkovsky, Emil; Neese, Frank; Wieghardt, Karl; Chirik, Paul J.
- Book ID
- 111977899
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 514 KB
- Volume
- 128
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The ligand __N,N′__‐bis(6‐methyl‐2‐pyridylmethyl)‐__N,N′__‐bis(2‐pyridylmethyl)ethane‐1,2‐diamine (L~6~^2^2M) has allowed to prepare the new Fe^II^ complex [(L~6~^2^2M)FeCl~2~] (1), and to compare its structural and spectroscopic characteristics with [(L~6~^2^2M)FeCl]PF~6~ (2). The mole