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X-ray crystal and molecular structure of bis(biphenylyl-2)tin(IV) dichloride, a discrete, molecular, organotin chloride

✍ Scribed by Baxter, J. L.; Holt, E. M.; Zuckerman, J. J.


Book ID
126018322
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
682 KB
Volume
4
Category
Article
ISSN
0276-7333

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Organotin(IV) compounds of 2-thiopyridin
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Dicyclohexyltin(IV) bis(2\_pyridylthiolate), compound 1, crystallizes in the orthorhombic system, a = 16&N(3), b=40.315(8) and c =7.113(3). Its molecular structure is best described as a tetrahedron, based on the two carbon-tin and the two sulfur-tin bonds, which is however strongly distorted as a c