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Organocatalytic Enantioselective Synthesis of α-Hydroxy Phosphonates

✍ Scribed by Samanta, Sampak; Zhao, Cong-Gui

Book ID
127025684
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
32 KB
Volume
128
Category
Article
ISSN
0002-7863

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Reaction of phosphonate anions with enantiomerically pure (camphorsulfonyl)oxaziridines results in formation of nonracemic ot-hydroxy phosphonates. This enantioselective hydroxylation methodology provides convenient access to optically active ot-hydroxy phosphonates and their corresponding phosphoni

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The enantioselective synthesis of a-aminoand a-hydroxy phosphonates by catalytic processes has attracted considerable interest in the last few years, not least because of the pharmaceutical interest in such compounds. This article contains a compilation of the asymmetric synthesis methods developed