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ChemInform Abstract: Organocatalytic Enantioselective Synthesis of Tertiary α-Hydroxy Phosphonates.

✍ Scribed by Hyun Joo Lee; Ji Hyeon Kim; Dae Young Kim


Publisher
John Wiley and Sons
Year
2011
Weight
28 KB
Volume
42
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Enantioselective Sy
✍ D. M. POGATCHNIK; D. F. WIEMER 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

Enantioselective Synthesis of α-Hydroxy Phosphonates via Oxidation with (Camphorsulfonyl)oxaziridines. -Chiral dichloro oxaziridines (OXA) are used for the enantioselective introduction of the hydroxy group to prochiral phosphonates. The (+)-reagent favors the formation of (S)-products. Phosphonate