✦ LIBER ✦

Catalytic Concepts for the Enantioselective Synthesis of α-Amino and α-Hydroxy Phosphonates

✍ Scribed by Harald Gröger; Benedikt Hammer

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 116 KB
Volume: 6
Category: Article
ISSN: 0947-6539
DOI: 10.1002/(sici)1521-3765(20000317)6:6<943::aid-chem943>3.0.co;2-4

No coin nor oath required. For personal study only.

✦ Synopsis

The enantioselective synthesis of a-aminoand a-hydroxy phosphonates by catalytic processes has attracted considerable interest in the last few years, not least because of the pharmaceutical interest in such compounds. This article contains a compilation of the asymmetric synthesis methods developed to date. The described synthetic routes are based on different catalytic concepts, namely, hydrogenation, reductions, dihydroxylation, aminohydroxylation, and hydrophosphonylation.

📜 SIMILAR VOLUMES

The Direct Catalytic Enantioselective Sy

The Direct Catalytic Enantioselective Synthesis of Protected Aryl β-Hydroxy-α-Amino Acids

✍ Michael C. Willis; Gary A. Cutting; Vincent J.-D. Piccio; Matthew J. Durbin; M 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 96 KB

The Direct Catalytic Enantioselective Sy

The Direct Catalytic Enantioselective Synthesis of Protected Aryl β-Hydroxy-α-Amino Acids

✍ Michael C. Willis; Gary A. Cutting; Vincent J.-D. Piccio; Matthew J. Durbin; M 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 96 KB 👁 1 views

Direct Catalytic Enantioselective α-Amin

Direct Catalytic Enantioselective α-Aminoxylation of Ketones: A Stereoselective Synthesis of α-Hydroxy and α,α′-Dihydroxy Ketones

✍ Anders Bøgevig; Henrik Sundén; Armando Córdova 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 127 KB

Direct Catalytic Enantioselective α-Amin

Direct Catalytic Enantioselective α-Aminoxylation of Ketones: A Stereoselective Synthesis of α-Hydroxy and α,α′-Dihydroxy Ketones

✍ Anders Bøgevig; Henrik Sundén; Armando Córdova 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 127 KB

Diastereoselective and Enantioselective

Diastereoselective and Enantioselective Synthesis of Tertiary α-Hydroxy Phosphonates through Hydrogen-Bond Catalysis

✍ Vijaya Bhasker Gondi; Koji Hagihara; Viresh H. Rawal 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 350 KB

Diastereoselective and Enantioselective

Diastereoselective and Enantioselective Synthesis of Tertiary α-Hydroxy Phosphonates through Hydrogen-Bond Catalysis

✍ Vijaya Bhasker Gondi; Koji Hagihara; Viresh H. Rawal 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 349 KB