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Enantioselective synthesis of α-hydroxy phosphonates via oxidation with (camphorsulfonyl)oxaziridines

✍ Scribed by Diana M. Pogatchnik; David F. Wiemer

Book ID: 104257067
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 183 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00705-3

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✦ Synopsis

Reaction of phosphonate anions with enantiomerically pure (camphorsulfonyl)oxaziridines results in formation of nonracemic ot-hydroxy phosphonates. This enantioselective hydroxylation methodology provides convenient access to optically active ot-hydroxy phosphonates and their corresponding phosphonic acids.

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