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Organic reactions at high pressure. Wittig reaction of hindered ketones with nonstabilized ylides.

✍ Scribed by William G. Dauben; James J. Takasugi

Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 190 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)96514-6

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✦ Synopsis

The Wittig reaction between n-butylidenetriphenylphosphorane and a series of cyclohexanones of increasing steric hindrance around the carbonyl group has been studied at 7 kbar and 15 kbar pressure (0.75-1.5 GPa) and at 40 "C.

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