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One-Bond, Two-Bond, and Three-Bond Mechanisms in Thermal Deazetizations of 2,3-Diazabicyclo[2.2.2]oct-2-enes, trans -Azomethane, and 2,3-Diazabicyclo[2.2.1]hept-2-ene

โœ Scribed by Khuong, Kelli S.; Houk, K. N.


Book ID
126063409
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
682 KB
Volume
125
Category
Article
ISSN
0002-7863

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Thermal deasetation of difluoro-and tetrafluoro-2,3-diasabicyclo[3.2.0lhept-2-enes proceed via two parallel mechanistic pathways, one involving formation of a diradical via simple N2 loss, and the other proceeding via a retro-dipolar cycloadd~on process. A key finding was the absence of isolation of