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Mechanism of Thermal Deazetization of 2,3-Diazabicyclo[2.2.1]hept-2-ene and Its Reaction Dynamics in Supercritical Fluids

โœ Scribed by Reyes, Mayra B.; Carpenter, Barry K.


Book ID
127122000
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
256 KB
Volume
122
Category
Article
ISSN
0002-7863

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Thermal deasetation of difluoro-and tetrafluoro-2,3-diasabicyclo[3.2.0lhept-2-enes proceed via two parallel mechanistic pathways, one involving formation of a diradical via simple N2 loss, and the other proceeding via a retro-dipolar cycloadd~on process. A key finding was the absence of isolation of