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Dynamics of the thermal decomposition of 2,3-diazabicyclo[2.2.1]hept-2-ene

โœ Scribed by Simpson, C. J. S. M.; Wilson, G. J.; Adam, W.


Book ID
126438100
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
598 KB
Volume
113
Category
Article
ISSN
0002-7863

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Thermal deasetation of difluoro-and tetrafluoro-2,3-diasabicyclo[3.2.0lhept-2-enes proceed via two parallel mechanistic pathways, one involving formation of a diradical via simple N2 loss, and the other proceeding via a retro-dipolar cycloadd~on process. A key finding was the absence of isolation of